Important Equations
Angular Momentum
Lx=21(L++L−)
Ly=2i1(L+−L−)
Lz∣l,m⟩=ℏm∣l,m⟩
L±∣l,m⟩=ℏl(l+1)−m(m±1)∣l,m±1⟩
Lx2∣l,m⟩=Lx(Lx∣l,m⟩)
Ly2∣l,m⟩=Ly(Ly∣l,m⟩)
Lz2∣l,m⟩=Lz(Lz∣l,m⟩)
L2=Lx2+Ly2+Lz2
L2∣l,m⟩=ℏ2l(l+1)∣l,m⟩
Spins
Sx=21(S++S−)
Sy=2i1(S+−S−)
Sz∣s,m⟩=ℏm∣s,m⟩
S±∣s,m⟩=ℏs(s+1)−m(m±1)∣s,m±1⟩
S2∣s,m⟩=ℏ2s(s+1)∣s,m⟩
Sx=2ℏ[0110]
Sy=2ℏ(0i−i0)
Sz=2ℏ(100−1)
S2=43ℏ2(1001)
S+=ℏ(0010)
S−=ℏ(0100)
↑=(10)
↓=(01)
P+z=∣⟨↑∣χ⟩∣2=∣(10)(χ0,0χ1,0)∣2
P−z=∣⟨↓∣χ⟩∣2=∣(01)(χ0,0χ1,0)∣2
P+y=⟨χ+y∣χ⟩
P−y=⟨χ−y∣χ⟩
Syχ+y=2ℏχ+y
Syχ−y=2ℏχ−y
⟨Sz⟩=⟨χ∣Sz∣χ⟩=χ∗Szχ
⟨Sx⟩=⟨χ∣Sx∣χ⟩=χ∗Ssχ
⟨Sy⟩=⟨χ∣Sy∣χ⟩=χ∗Syχ
The hydrogen atom
Rn,l(r)=r1ρl+1e−ρv(ρ)
⟨Ψ∣H∣Ψ⟩=∑E×P
Energy levels: En=n2E0
Clebsch-Gordan coefficients
l and s tell which table to look at. m and ss or sz tell which column to look at.